IUPAC Naming of Elements with Atomic Number Above 100

Chemistry · Periodic Classification Of Properties · NEET

For any element with atomic number above 100, IUPAC gives a temporary name by spelling out each digit of the atomic number using number roots, then adding "-ium" at the end. The symbol is made from the first letter of each root. Memory hook: NIL-UN-BI-TRI = 0-1-2-3, so just read the digits out loud and glue them together.
IUPAC Naming: Z = 119119++ununennun + un + enn + ium = ununenniumSymbol = UueDigit roots (NCERT Table 3.4):0 nil 1 un 2 bi 3 tri 4 quad5 pent 6 hex 7 sept 8 oct 9 ennRule 1: spell each digit's root in orderRule 2: add "-ium" at the endRule 3: symbol = first letter of each root
Naming Z = 119: spell each digit (1,1,9) as its root (un, un, enn), add "-ium" to get ununennium, and take the first letter of each root for the symbol Uue.

Your doubts, answered

How do I write the IUPAC name for atomic number 119 step by step?

Break the number into single digits: 1, 1, 9. Now replace each digit with its root: 1 = un, 1 = un, 9 = enn. Join them in order: un + un + enn = ununenn. Add '-ium' at the end (but drop the double 'i' or double 'n' if it looks odd) to get ununennium. So Z = 119 is ununennium, symbol Uue. Do not try to guess a real name like the way older elements got named; for NEET you only spell out the digits.

What are all the number roots I must memorise for this topic?

There are only ten roots, one for each digit 0 to 9: 0 = nil, 1 = un, 2 = bi, 3 = tri, 4 = quad, 5 = pent, 6 = hex, 7 = sept, 8 = oct, 9 = enn. This is straight from NCERT Table 3.4. If you know these ten, you can name any element above 100. A common exam trick is to give you the name and ask for the atomic number, so learn the roots both ways (name to number and number to name).

How do I make the three letter symbol for such an element?

Take the first letter of each root you used, in the same order, and capitalise only the first letter. For Z = 114 the roots are un (1), un (1), quad (4), so the symbol is Uuq. For Z = 119 the roots are un, un, enn, so the symbol is Uue. The symbol always has three letters because the atomic number always has three digits in this range.

Why do we even use these strange names instead of real names?

NCERT explains that naming a new element used to be the right of the discoverer, and this caused fights (for example one element was called both Kurchatovium and Rutherfordium by different countries). Also these very heavy atoms are so unstable that only a few atoms are ever made, so the discovery takes long to confirm. So IUPAC gives a temporary systematic name from the atomic number until the real name is voted on and approved.

Is unnilunium the same as mendelevium?

Yes. Unnilunium is the systematic name for Z = 101, because un = 1, nil = 0, un = 1 gives 101. The permanent IUPAC name for element 101 is Mendelevium (Md). NEET 2020 asked exactly this match. Once an element gets its official permanent name, the systematic name is only used in old questions, but NEET still tests it, so remember both the systematic name and the real name for elements like Md (101), Lr (103), Sg (106).

How do I go from a systematic name back to the atomic number?

Split the name into its roots (they always come before '-ium'), then convert each root back to a digit. Example: Unnilseptium = un (1) + nil (0) + sept (7) = 107. Example: Ununoctium = un (1) + un (1) + oct (8) = 118. Reading the roots in order gives you the digits of the atomic number directly.

⚠️ The NEET trap
Writing Z = 119 as unununnium because it starts with two 'un' roots.
Unununnium is un-un-un = 111, not 119. For 119 the last digit 9 is 'enn', so it is un-un-enn = ununennium (Uue). Always convert digit by digit; do not repeat 'un' three times unless the number is actually 111.
🧠 9 = enn, not un. If you see a 9, think 'ENN' like the last letter sound in 'nine'.

Real NEET questions

NEET 2022

The IUPAC name of an element with atomic number 119 is:

A · ununennium
B · unnilennium
C · unununnium
D · ununoctium
Solution: Split 119 into digits 1, 1, 9. Roots: 1 = un, 1 = un, 9 = enn. Join and add -ium: un-un-enn-ium = ununennium (symbol Uue). Check the distractors: unnilennium = 1,0,9 = 109 (wrong digits); unununnium = 1,1,1 = 111; ununoctium = 1,1,8 = 118. Only option A matches 119.
NEET 2020

Match the IUPAC provisional (systematic) names with their official names. (a) Unnilunium (b) Unniltrium (c) Unnilhexium (d) Unununnium with (i) Mendelevium (ii) Lawrencium (iii) Seaborgium (iv) Darmstadtium. Which one is correct?

A · (c)-(iii)
B · (d)-(iv)
C · (a)-(i)
D · (b)-(ii)
Solution: Convert each systematic name using the roots. Unnilunium = un(1) nil(0) un(1) = 101 = Mendelevium (Md), so (a)-(i) is correct. Check others: Unniltrium = 1,0,3 = 103 = Lawrencium (so (b)-(ii) is also chemically right, but among the single-pair options the keyed answer is C). Unnilhexium = 1,0,6 = 106 = Seaborgium. Unununnium = 1,1,1 = 111 = Roentgenium (Rg), NOT Darmstadtium (which is 110), so (d)-(iv) is wrong. The correct listed choice is (a)-(i).
NEET 2022 / 2026

Identify the incorrect statement. (Option B stated: The IUPAC name of the element with atomic number 107 is Unnilseptium.)

A · Largest and smallest among Mg, Mg2+, Al, Al3+ are Al and Mg2+ respectively
B · The IUPAC name of the element with atomic number 107 is Unnilseptium
C · The similarity of Li with Mg is the diagonal relationship
D · Oxidation state and covalency of Al in [AlCl(H2O)5]2+ are 3 and 6
Solution: For the naming part (option B): 107 = un(1) nil(0) sept(7) = Unnilseptium, so B is a CORRECT statement. The incorrect statement is A: among Mg, Mg2+, Al, Al3+ the largest is neutral Mg (not Al) and the smallest is Al3+ (not Mg2+). So the answer to 'identify the incorrect statement' is A, and this PYQ confirms Z = 107 = Unnilseptium is right.

Solved Periodic Classification Of Properties NEET PYQs

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Frequently asked

Do I have to memorise the permanent names of elements above 100 for NEET?

You must know the systematic method (the digit roots) for sure, because that is directly asked. Also learn a few common matches that NEET has asked: 101 = Mendelevium (Md), 103 = Lawrencium (Lr), 106 = Seaborgium (Sg), 110 = Darmstadtium (Ds), 111 = Roentgenium (Rg). Memorising all of them is not needed, but these appear in match questions.

Why does the symbol always have three letters?

Because every atomic number above 100 has exactly three digits (100 to 999 range in practice), and you take one letter for each digit's root. So the symbol is always three letters, like Uuq for 114 or Uue for 119.

What suffix is always added at the end of these names?

The suffix is always '-ium'. You spell out all the digit roots first and then add -ium. This is why every systematic name of a heavy element ends in -ium.

Is unnilseptium a real element name or a temporary one?

It is a temporary systematic name for Z = 107. The permanent IUPAC name for 107 is Bohrium (Bh). NEET still uses the systematic name in questions, so you should be able to convert Unnilseptium back to 107 quickly.

How is this different from IUPAC naming in organic chemistry?

Both are IUPAC systems but they are unrelated. Organic IUPAC naming builds a name from the carbon chain and functional groups. Here, for heavy elements, the name is built only from the digits of the atomic number plus -ium. Do not mix the two rule sets.