Mendeleev's Eka-Aluminium and Eka-Silicon Predictions Explained

Chemistry · Periodic Classification Of Properties · NEET

Mendeleev left empty boxes in his table for elements not yet found. He predicted their properties and named them "eka-aluminium" and "eka-silicon" (eka = one step below in the same group). Later, gallium turned out to be eka-aluminium and germanium turned out to be eka-silicon, and their real properties matched his guesses almost exactly. Memory hook: "Eka = one below, so eka-Al sits below Al (Ga), eka-Si sits below Si (Ge)."
Mendeleev's Gaps: eka-elements → real elementsGroup 13Group 14Al (known)Si (known)eka-Al (gap)eka-Si (gap)GalliumGermaniumDashed box = predicted gap • Green box = real element found later
Mendeleev left dashed gaps below Al and Si and predicted their properties. Those gaps were later filled by gallium (eka-aluminium) and germanium (eka-silicon).

Your doubts, answered

What does the word 'eka' mean in eka-aluminium?

Eka is a Sanskrit word meaning 'one'. Mendeleev used it to mean 'one place below' the known element in the same group. So eka-aluminium means the missing element sitting one box below aluminium. Eka-silicon means the missing element one box below silicon. It is just his naming style for a gap, not a real element name.

Which real elements are eka-aluminium and eka-silicon?

Eka-aluminium is gallium (Ga), discovered in 1875. Eka-silicon is germanium (Ge), discovered in 1886. When their true properties were measured, they matched Mendeleev's predicted values very closely. This match made scientists trust his periodic table.

Why did Mendeleev leave empty gaps in his table?

He kept elements with similar properties in the same group. Sometimes the next known element did not fit the pattern, so he left an empty box instead of forcing a wrong element in. He believed a real element that fit the gap was simply not discovered yet. This is why his table had blank spaces on purpose.

How could Mendeleev predict properties of an element nobody had found?

He used the trend in the group. He took the average of the neighbours (the element above, below, left, and right in the table) to estimate atomic mass, density, melting point, and formula of oxides. For eka-silicon he predicted mass about 72 and a dioxide; germanium later showed mass 72.6 and forms GeO2. For NEET, remember this shows periodic properties change in a regular, predictable way.

What is the difference between eka-aluminium and eka-boron?

They are different gaps in different groups. Eka-boron is the element one below boron, which turned out to be scandium (Sc). Eka-aluminium is one below aluminium, which turned out to be gallium (Ga). Eka-silicon is one below silicon, which is germanium (Ge). Do not mix them up: eka-B = Sc, eka-Al = Ga, eka-Si = Ge.

Why do these predictions matter for the periodic law?

They proved that properties are a periodic function of atomic weight, as Mendeleev claimed. Because the guesses came true, his periodic table was accepted over rivals. In NEET, a common one-line fact is: the success of these predictions was the biggest merit of Mendeleev's table.

⚠️ The NEET trap
Eka-silicon is gallium and eka-aluminium is germanium.
Eka-aluminium is gallium (Ga) and eka-silicon is germanium (Ge). Match by the group: eka-Al sits below Al, eka-Si sits below Si.
🧠 Same letter pairs: Al and Ga are both group 13; Si and Ge are both group 14. Keep the group and you keep the answer.

Solved Periodic Classification Of Properties NEET PYQs

Try the real previous-year questions from this chapter — each with the answer and a full solution.

See all 28 Periodic Classification Of Properties NEET PYQs ›
Next concept: Merits and Defects of Mendeleev's Periodic TableKeep learning — 2 minFeeling ready? Solve the Periodic Classification Of Properties NEET PYQs ›Or practice on your phone — get the free MedicNEET app ›

Frequently asked

Is eka-aluminium the same as gallium?

Yes. Eka-aluminium was Mendeleev's placeholder name for the missing element below aluminium. It was later discovered and named gallium (Ga).

What did Mendeleev predict for eka-silicon?

He predicted an atomic mass near 72, a grey metal-like solid, an oxide of the form EO2 (a dioxide), and a chloride ECl4. Germanium later matched all of these closely.

What is eka-boron?

Eka-boron is the gap one place below boron. It was later filled by scandium (Sc). Note it is different from eka-aluminium (gallium).

Why are these predictions important in NEET?

They are the strongest proof of Mendeleev's periodic law and a favourite exam fact. Questions often ask you to match eka-names with the modern element.

What does 'eka' come from?

Eka is Sanskrit for 'one', meaning one step below the named element in the same group of the table.