NEET 2021 · ChemistryIsomerismPrevious Year Question

Ethylenediaminetetraacetate (EDTA) ion is:

Answer: (C) Hexadentate ligand with four “O” and two “N” donor atoms. \textbf{Answer:} (C) Hexadentate ligand with four “O” and two “N” donor atoms.

  1. A.Bidentate ligand with two “N” donor atoms
  2. B.Tridentate ligand with three “N” donor atoms
  3. C.Hexadentate ligand with four “O” and two “N” donor atoms
  4. D.Unidentate ligand

Correct Answer

(C) Hexadentate ligand with four “O” and two “N” donor atoms

Solution & Explanation

\textbf{Answer:} (C) Hexadentate ligand with four “O” and two “N” donor atoms. \textbf{Solution:} Denticity is the number of donor atoms of a ligand that bind to the metal centre simultaneously. The ethylenediaminetetraacetate ion, , has six donor sites: two amine nitrogen atoms (from the ethylenediamine backbone) and four carboxylate oxygen atoms (one from each group). All six can coordinate to a single metal ion, wrapping around it and forming five chelate rings. EDTA is therefore a hexadentate chelating ligand with four O and two N donor atoms. Hence option (C) is correct.

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