The given graph (drawn at constant temperature ) is a representation of the kinetics of a reaction. The plot of versus is a horizontal straight line parallel to the -axis, i.e. is constant and independent of . The and axes for zero order and first order reactions, respectively, are:
Answer: (C) zero order ( rate, concentration); first order (, concentration). \textbf{Answer:} (C) zero order ( rate, concentration); first order (, concentration) \textbf{Solution:} A horizontal line means the -quantity does not change as the -quantity changes.

- A.zero order ( concentration, time); first order (, concentration)
- B.zero order ( concentration, time); first order ( rate constant, concentration)
- C.zero order ( rate, concentration); first order (, concentration)✓
- D.zero order ( rate, concentration); first order ( rate, )
Correct Answer
(C) zero order ( rate, concentration); first order (, concentration)
Solution & Explanation
\textbf{Answer:} (C) zero order ( rate, concentration); first order (, concentration) \textbf{Solution:} A horizontal line means the -quantity does not change as the -quantity changes. For a \textbf{zero order} reaction the rate is independent of concentration: , so plotting against concentration gives a horizontal line. For a \textbf{first order} reaction is independent of the initial concentration, so plotting against concentration is also horizontal. Hence zero order: rate, concentration; first order: , concentration.
