Radioactive Decay Law: N = N0 e^(-lambda t) Derivation

Physics · nuclei · NEET

The radioactive decay law says the number of nuclei that decay per second is directly proportional to the number of undecayed nuclei present. Writing this as dN/dt = -lambda N and integrating gives N = N0 e^(-lambda t), where N0 is the starting number, N is the number left after time t, and lambda is the decay constant. Memory hook: "rate depends on how many are left" - fewer nuclei means slower decay, so the curve falls fast at first and then flattens.
NtN0N0/2T (half-life)N0/42TN = N0 e^(-lambda t)falls fast, then flattens
Exponential decay curve for N = N0 e^(-lambda t): the number of undecayed nuclei halves every half-life T (N0 to N0/2 to N0/4), giving a steep-then-flat curve rather than a straight line.

Your doubts, answered

Why is there a minus sign in dN/dt = -lambda N?

N is the number of nuclei still left (not yet decayed). As time passes this number falls, so its rate of change dN/dt must be negative. The quantity lambda and N are both positive, so we put a minus sign to make the right side negative and match the physical fact that N decreases. If you drop the minus sign you would be saying nuclei are being created, which is wrong.

How do I integrate dN/dt = -lambda N to get the exponential?

Separate the variables: dN/N = -lambda dt. Integrate both sides: integral of dN/N gives ln N, and integral of -lambda dt gives -lambda t + C. So ln N = -lambda t + C. At t = 0, N = N0, so C = ln N0. Then ln N - ln N0 = -lambda t, which is ln(N/N0) = -lambda t. Taking exponential of both sides gives N/N0 = e^(-lambda t), so N = N0 e^(-lambda t).

In the formula, is N the number of atoms, the mass, or the activity?

In the pure decay law N = N0 e^(-lambda t), N is the NUMBER of undecayed nuclei. But the same exponential shape works for mass (m = m0 e^(-lambda t)) and for activity (A = A0 e^(-lambda t)), because mass is proportional to number and activity A = lambda N is also proportional to number. So all three decay with the same lambda and same half-life. Just be careful which quantity the question gives you.

Does the decay rate change with temperature, pressure or chemical state?

No. Radioactive decay comes from inside the nucleus, so lambda is fixed for a given nuclide and does not change with temperature, pressure, or whether the atom is in a compound. This is a favourite NEET point. Only the number of nuclei present affects how many decay per second, not the outside conditions.

What does e^(-lambda t) mean physically?

e^(-lambda t) is the fraction of the original nuclei that are STILL present after time t. At t = 0 it equals 1 (all present). As t grows it shrinks toward 0. When t = 1/lambda (the mean life), e^(-1) = 0.37, so about 37 percent are left. It never becomes exactly zero, which is why we use half-life to describe the pace instead of a total finish time.

Why does the graph of N vs t curve instead of falling in a straight line?

Because the number decaying each second is proportional to how many are left. When many nuclei are present, many decay per second, so N drops steeply. As N gets smaller, fewer decay per second, so the fall slows down. This gives a curve that is steep at first and flattens later - an exponential decay curve, not a straight line.

⚠️ The NEET trap
Students write N = N0 e^(-lambda t) and think that after one mean life (t = 1/lambda) the sample is fully decayed, or they treat the decay as linear and assume half the sample gone means the other half goes in the same next time interval linearly.
After t = 1/lambda only e^(-1) = 0.37 (about 37 percent) of nuclei remain, not zero. Decay is exponential, so equal FRACTIONS are lost in equal times, not equal AMOUNTS. Half-life T = 0.693/lambda is the time for the number to halve, and it stays halving every T no matter how much is left.
🧠 e^(-1) is 0.37, not 0 - a radioactive sample never fully empties, it only halves again and again.
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Frequently asked

State the radioactive decay law in one line.

The rate of decay of a radioactive sample is directly proportional to the number of undecayed nuclei present at that instant: dN/dt = -lambda N, giving N = N0 e^(-lambda t).

What is the SI unit of the decay constant lambda?

Since lambda t must be dimensionless, lambda has units of per second (s^-1). It represents the fraction of nuclei that decay per unit time.

How is the decay law related to half-life?

Set N = N0/2 in N = N0 e^(-lambda t). This gives 1/2 = e^(-lambda T), so lambda T = ln 2, meaning half-life T = 0.693/lambda. Half-life and lambda are inversely related.

Can the decay law predict when a single nucleus will decay?

No. Radioactive decay is a random (statistical) process. The law only predicts the behaviour of a large number of nuclei on average; it cannot say when any one particular nucleus will decay.

Is the decay law valid for activity as well?

Yes. Since activity A = lambda N, multiplying the decay law by lambda gives A = A0 e^(-lambda t). Activity falls with the same decay constant and half-life as the number of nuclei.