P700 and P680 Reaction Centres in Photosynthesis

Biology · Photosynthesis in Higher Plants · NEET

P700 and P680 are the single chlorophyll a molecules at the "reaction centre" of the two photosystems. P700 belongs to Photosystem I and absorbs light best at 700 nm; P680 belongs to Photosystem II and absorbs best at 680 nm. Memory hook: the letter "P" stands for pigment, and the number is the exact wavelength (in nm) it absorbs — 700 for one, 680 for the other.
Two Reaction Centres of the Light ReactionPhotosystem II (PS II)P680680 nmsplits water, releases O2Photosystem I (PS I)P700700 nmreduces NADP+ to NADPHelectronsBoth centres are single chlorophyll a molecules
P680 (PS II) absorbs at 680 nm and is linked to water splitting; P700 (PS I) absorbs at 700 nm and reduces NADP+. Both reaction centres are single chlorophyll a molecules.

Your doubts, answered

Is P700 in PS I or PS II? (this trips up most students)

P700 is in Photosystem I (PS I) and P680 is in Photosystem II (PS II). Remember the bigger number goes with the smaller Roman numeral: P700 = PS I, P680 = PS II. The systems are named by the order they were discovered, not the order they work in the light reaction (PS II actually acts first).

Why is it called P700 and P680?

The 'P' means pigment (the reaction-centre chlorophyll a), and the number is the wavelength of red light it absorbs most strongly. In PS I the reaction-centre chlorophyll a has an absorption peak at 700 nm, so it is named P700. In PS II it peaks at 680 nm, so it is named P680. NCERT states this directly.

Are P700 and P680 the same molecule or different?

Both are chlorophyll a molecules, so chemically they are the same pigment type. But they sit in different protein environments in PS I and PS II, which shifts their absorption peaks slightly — one to 700 nm, the other to 680 nm. So they are the same pigment (chlorophyll a) but function as two different reaction centres.

Which one has higher-energy light, P680 or P700?

Shorter wavelength means higher energy. 680 nm is shorter than 700 nm, so P680 (PS II) uses slightly higher-energy light than P700 (PS I). This matches the Z-scheme: PS II must lift electrons high enough to eventually reduce NADP+ after passing through PS I.

Does the reaction centre have all the pigments?

No. Each photosystem has hundreds of pigments in the antenna (light-harvesting complex) that only trap and funnel light. Just one single chlorophyll a molecule at the centre — P700 or P680 — actually loses the excited electron and starts the electron transport. That single molecule is the reaction centre.

⚠️ The NEET trap
P680 belongs to Photosystem I because 680 is close to 700.
P680 belongs to Photosystem II (absorbs 680 nm); P700 belongs to Photosystem I (absorbs 700 nm).
🧠 NTA loves swapping the pairs. Lock it: P700 -> PS I, P680 -> PS II. Higher number pairs with the lower Roman numeral.

Real NEET questions

2023

The reaction centre in PS II has an absorption maxima at

A · 680 nm
B · 700 nm
C · 660 nm
D · 780 nm
Solution: Each photosystem has one reaction-centre chlorophyll a. In PS II this chlorophyll a absorbs maximally at 680 nm and is called P680. (In PS I it peaks at 700 nm and is called P700.) So the PS II reaction centre has an absorption maximum at 680 nm. NCERT Class 11, Ch 11, p.138.
2026

Which pigment has an absorption peak at 700 nm in the photosynthetic reaction centre PS I (P700)?

A · Chlorophyll b
B · Chlorophyll a
C · Xanthophylls
D · Carotenoids
Solution: The single reaction-centre molecule of every photosystem is chlorophyll a. In PS I this chlorophyll a has an absorption peak at 700 nm, so it is named P700. (In PS II the reaction-centre chlorophyll a absorbs at 680 nm, P680.) Accessory pigments like chlorophyll b, xanthophylls and carotenoids are only in the antenna, not the reaction centre.

Solved Photosynthesis in Higher Plants NEET PYQs

Try the real previous-year questions from this chapter — each with the answer and a full solution.

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Frequently asked

What is a reaction centre in photosynthesis?

It is the single chlorophyll a molecule in a photosystem that receives energy from the antenna pigments and releases an excited electron to start the electron transport chain. P700 (PS I) and P680 (PS II) are the two reaction centres.

What is the difference between P700 and P680 in one line?

P700 is the reaction-centre chlorophyll a of PS I that absorbs light at 700 nm; P680 is the reaction-centre chlorophyll a of PS II that absorbs light at 680 nm.

Which reaction centre is linked to the splitting of water?

P680 (PS II). The splitting of water (photolysis) that releases O2 is associated with Photosystem II, which contains P680.

Are P700 and P680 accessory pigments?

No. They are reaction-centre chlorophyll a molecules. Accessory pigments (chlorophyll b, carotenoids, xanthophylls) sit in the antenna and only pass energy to these reaction centres.

Why does NEET ask about P700 and P680 so often?

It is a direct one-line NCERT fact that is very easy to twist. Questions swap the wavelengths (700/680) or swap the photosystems (PS I/PS II), so knowing the exact pairing gives a guaranteed mark.