The incorrect statement among the following is:
Answer: (D) (d) Most of the trivalent lanthanoid ions are colourless in the solid state.. \textbf{Answer:} (d) Most of the trivalent lanthanoid ions are colourless in the solid state.
- A.(a) Lanthanoids are good conductors of heat and electricity.
- B.(b) Actinoids are highly reactive metals, especially when finely divided.
- C.(c) Actinoid contraction is greater for element to element than lanthanoid contraction.
- D.(d) Most of the trivalent lanthanoid ions are colourless in the solid state.✓
Correct Answer
(D) (d) Most of the trivalent lanthanoid ions are colourless in the solid state.
Solution & Explanation
\textbf{Answer:} (d) Most of the trivalent lanthanoid ions are colourless in the solid state. (This is the incorrect statement.) \textbf{Solution:} (a) Lanthanoids are metals and are good conductors of heat and electricity — correct. (b) Actinoids are highly reactive metals, especially in a finely divided state — correct. (c) The element-to-element contraction is greater in actinoids than in lanthanoids because the electrons shield the nuclear charge poorly — correct. (d) MOST trivalent lanthanoid ions () are actually coloured (due to f-f transitions); only a few such as and are colourless. So the statement that most are colourless is incorrect. Hence the incorrect statement is (d).
