NEET 2021 · ChemistryLanthanoidsPrevious Year Question

The incorrect statement among the following is:

Answer: (D) (d) Most of the trivalent lanthanoid ions are colourless in the solid state.. \textbf{Answer:} (d) Most of the trivalent lanthanoid ions are colourless in the solid state.

  1. A.(a) Lanthanoids are good conductors of heat and electricity.
  2. B.(b) Actinoids are highly reactive metals, especially when finely divided.
  3. C.(c) Actinoid contraction is greater for element to element than lanthanoid contraction.
  4. D.(d) Most of the trivalent lanthanoid ions are colourless in the solid state.

Correct Answer

(D) (d) Most of the trivalent lanthanoid ions are colourless in the solid state.

Solution & Explanation

\textbf{Answer:} (d) Most of the trivalent lanthanoid ions are colourless in the solid state. (This is the incorrect statement.) \textbf{Solution:} (a) Lanthanoids are metals and are good conductors of heat and electricity — correct. (b) Actinoids are highly reactive metals, especially in a finely divided state — correct. (c) The element-to-element contraction is greater in actinoids than in lanthanoids because the electrons shield the nuclear charge poorly — correct. (d) MOST trivalent lanthanoid ions () are actually coloured (due to f-f transitions); only a few such as and are colourless. So the statement that most are colourless is incorrect. Hence the incorrect statement is (d).

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