Potentiometer: Comparing EMF of Two Cells

Physics · Current Electricity · NEET

A potentiometer compares the EMF of two cells by finding the balance length for each. Since the wire has a constant potential drop per cm (potential gradient), the balance length is directly proportional to EMF, so E1/E2 = L1/L2. Memory hook: "longer balance means bigger EMF" — the stronger cell needs more wire to be balanced.
Comparing EMF of Two Cells on a PotentiometerABDriver cell (EMF > test cells)jockeybalance length LGreads 0 at balanceTest cell(E1 or E2)At balance: E = k L → E1/E2 = L1/L2
The test cell is balanced when the galvanometer reads zero, so its EMF equals the potential drop k over the balance length L. Comparing two cells gives E1/E2 = L1/L2, with no current drawn from either cell.

Your doubts, answered

Why is E1/E2 = L1/L2? Where does this come from?

The driver cell sends a steady current through the long potentiometer wire, so the potential falls evenly along it. This fall per unit length is the potential gradient, k (in V/cm), and it is the same at every point. At the balance point the cell's EMF exactly equals the potential drop across the balanced length: E1 = k L1 and E2 = k L2. Divide the two equations and k cancels, giving E1/E2 = L1/L2. So you never even need to know k to compare two cells.

Does a potentiometer measure EMF or terminal voltage?

It measures true EMF, not terminal voltage. At the balance point the galvanometer shows zero, which means no current is drawn from the test cell. With zero current, there is no drop across the cell's internal resistance (I r = 0), so the terminal voltage equals the EMF. This is the whole reason a potentiometer is more accurate than a voltmeter, which always draws a small current and reads terminal voltage instead.

Why does the galvanometer read zero at balance and what does that mean?

The test cell's EMF and the potential drop across the balanced wire length oppose each other. When they are exactly equal, there is no net voltage to push current through the galvanometer, so it reads zero. This 'null' condition is key for NEET: no current means no I r loss, so you are reading the real EMF. Adjust the jockey until the galvanometer needle sits at zero — that contact point gives the balance length.

How do I use the sum and difference method for two cells?

Connect the two cells so they help each other (aiding), and the net EMF is E1 + E2, balanced at length L_sum. Then reverse one cell so they oppose, giving net EMF E1 - E2, balanced at length L_diff. Because balance length is proportional to net EMF: (E1 + E2)/(E1 - E2) = L_sum/L_diff. Solve this to get E1/E2. This is exactly what NEET 2016 asked.

Why must the driver cell's EMF be larger than the cells being compared?

The potentiometer can only balance a cell if the wire can supply a potential drop equal to that cell's EMF. The maximum drop available is across the full wire, set by the driver cell. If a test cell's EMF is greater than the total drop across the wire, no balance point exists anywhere and the galvanometer never reaches zero. So the driver (primary) cell must always have a higher EMF than any cell you compare.

⚠️ The NEET trap
Assuming the potentiometer reads the terminal voltage of the cell, or that some current flows through the test cell at balance.
At the balance point the galvanometer reads zero, so zero current is drawn from the test cell. With I = 0 there is no I r drop, so the potentiometer reads the true EMF, not the terminal voltage.
🧠 Balance = zero current = true EMF. If current flowed, you would read terminal voltage instead.

Real NEET questions

NEET 2016

A potentiometer wire is 100 cm long with a constant PD across it. Two cells in series give balance at 50 cm (aiding) and 10 cm (opposing). The ratio of their EMFs (E1 : E2) is:

A · 5 : 1
B · 5 : 4
C · 3 : 4
D · 3 : 2
Solution: Balance length is proportional to net EMF. Aiding: (E1 + E2) ∝ 50 cm. Opposing: (E1 - E2) ∝ 10 cm. Divide: (E1 + E2)/(E1 - E2) = 50/10 = 5. So E1 + E2 = 5(E1 - E2) → E1 + E2 = 5E1 - 5E2 → 6E2 = 4E1 → E1/E2 = 6/4 = 3/2. Answer: 3 : 2.
NEET 2021

In a potentiometer, a cell of EMF 1.5 V balances at 36 cm. If a 2.5 V cell replaces it, the balance length is:

A · 64 cm
B · 62 cm
C · 60 cm
D · 21.6 cm
Solution: For the same potential gradient, E1/E2 = L1/L2. So 1.5/2.5 = 36/L2. Rearrange: L2 = 36 × (2.5/1.5) = 36 × 5/3 = 60 cm. Answer: 60 cm.
NEET 2017

A potentiometer is an accurate and versatile device to measure EMF because the method involves:

A · cells
B · potential gradients
C · a condition of no current flow through the galvanometer
D · a combination of cells, galvanometer and resistances
Solution: At the balance (null) point the galvanometer reads zero, so no current is drawn from the test cell. With zero current there is no I r drop inside the cell, so the reading equals the true EMF (not terminal voltage). This null method is why the potentiometer is more accurate than a voltmeter. Answer: no current flow through the galvanometer.

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Frequently asked

What is the working principle used to compare two EMFs?

The potentiometer works on the principle that the potential drop across a uniform wire carrying a steady current is proportional to its length. Because balance length is proportional to EMF, comparing two cells reduces to comparing their balance lengths: E1/E2 = L1/L2.

What is the formula for comparing EMF of two cells?

E1/E2 = L1/L2, where L1 and L2 are the balance lengths for the two cells measured with the same potential gradient. The potential gradient cancels out, so you never need its value to compare cells.

Why is a potentiometer better than a voltmeter for measuring EMF?

A voltmeter always draws a small current, so it reads terminal voltage (EMF minus the I r drop). A potentiometer draws zero current at balance, so there is no I r drop and it reads the true EMF.

What happens if the galvanometer deflects to one side only?

One-sided deflection with no null point usually means a wrong connection or that the driver cell EMF is smaller than the test cell EMF. Check the polarity of the cells and make sure the driver (primary) cell has the larger EMF so a balance point exists on the wire.

How does the aiding and opposing method give the EMF ratio?

Aiding gives net EMF E1 + E2 balanced at L_sum; opposing gives E1 - E2 balanced at L_diff. Then (E1 + E2)/(E1 - E2) = L_sum/L_diff, which you solve to get E1/E2.