de Broglie Wavelength Formula and Derivation

Physics · Dual Nature Of Radiation And Matter · NEET

The de Broglie wavelength formula is lambda = h/p = h/(mv), where h is Planck's constant (6.63 x 10^-34 J.s), p is momentum, m is mass, and v is speed. It is derived by combining the photon energy E = hc/lambda with Einstein's E = mc^2, giving p = h/lambda for light, which de Broglie extended to all matter. Memory hook: "h over p, every particle wants to be a wave."
Deriving lambda = h/p from a photonWave viewE = hc / lambdaParticle viewE = m c^2hc/lambda = m c^2cancel one ch/lambda = m c = plambda = h / p
The de Broglie relation lambda = h/p is derived by equating the wave energy (E = hc/lambda) and particle energy (E = mc^2) of a photon, cancelling one c to reveal momentum p = mc, then extending it to all matter.

Your doubts, answered

How is the de Broglie wavelength formula derived step by step?

Start with a photon. Its energy has two expressions: E = hc/lambda (wave picture, Planck) and E = mc^2 (particle picture, Einstein). Set them equal: hc/lambda = mc^2. Cancel one c: hc/lambda = mc x c, so h/lambda = mc = p, where p = mc is the photon momentum. Rearranging gives lambda = h/p. de Broglie's bold step: this same relation must hold for ALL matter, not just light. So for any particle, lambda = h/p = h/(mv).

Why is it lambda = h/p and not h/mv?

They are the same thing. Momentum p = mv, so h/p = h/(mv). We write lambda = h/p as the general form because p is the true variable (it works even when you are given momentum directly or relativistic momentum). Use h/(mv) when you know mass and speed separately.

Where does the de Broglie idea actually come from?

Light already showed dual nature: it behaves as a wave (interference, diffraction) and as particles called photons (photoelectric effect). de Broglie argued nature should be symmetric, so if waves can act like particles, particles should act like waves. He assigned the same relation p = h/lambda to electrons, protons, and all matter. This wave is called a matter wave.

How can I write the formula in terms of kinetic energy?

For a non-relativistic particle, KE = p^2/(2m), so p = sqrt(2m x KE). Substitute into lambda = h/p to get lambda = h/sqrt(2m x KE). This is very useful in NEET problems where energy (in joules or eV) is given instead of speed.

Does the derivation change for an electron versus a photon?

The final formula lambda = h/p is identical for both. The difference is how you find p. For a photon, p = E/c = h/lambda directly. For a material particle like an electron, p = mv (or sqrt(2m x KE), or sqrt(2mqV) if accelerated through a potential). Same formula, different route to momentum.

⚠️ The NEET trap
Cancelling c wrong: from hc/lambda = mc^2, students write h/lambda = mc^2, forgetting to divide the right side by c too.
Divide BOTH sides by c: (hc/lambda)/c = (mc^2)/c gives h/lambda = mc = p. So lambda = h/p. Only one c cancels, leaving momentum p = mc, not mc^2.
🧠 One c cancels, one c stays. mc^2 divided by c is mc, which is momentum p.

Real NEET questions

NEET 2026

Match List I with List II. List-I: A. E = h.nu B. Diffraction and interference C. lambda = h/p D. Compton effect. List-II: I. de Broglie wavelength II. Particle nature of light III. Wave nature of light IV. Energy of photon. Choose the correct answer.

A · A-IV, B-I, C-II, D-III
B · A-IV, B-III, C-II, D-I
C · A-I, B-IV, C-III, D-II
D · A-IV, B-III, C-I, D-II
Solution: A. E = h.nu is the energy of a photon, so A-IV. B. Diffraction and interference show the wave nature of light, so B-III. C. lambda = h/p is exactly the de Broglie wavelength relation, so C-I. D. The Compton effect shows the particle nature of light, so D-II. Correct match: A-IV, B-III, C-I, D-II.
NEET 2017

The de Broglie wavelength of a neutron in thermal equilibrium with heavy water at temperature T (kelvin) and mass m is:

A · h/sqrt(mkT)
B · h/sqrt(3mkT)
C · 2h/sqrt(3mkT)
D · 2h/sqrt(mkT)
Solution: Step 1: A thermal neutron has average kinetic energy KE = (3/2)kT, where k is Boltzmann's constant. Step 2: Momentum p = sqrt(2m x KE) = sqrt(2m x (3/2)kT) = sqrt(3mkT). Step 3: Apply the de Broglie formula lambda = h/p = h/sqrt(3mkT). This is a direct use of the derived relation lambda = h/sqrt(2m x KE).

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Frequently asked

What is the de Broglie wavelength formula?

lambda = h/p = h/(mv), where h = 6.63 x 10^-34 J.s is Planck's constant, p is momentum, m is mass, and v is speed. In terms of kinetic energy it becomes lambda = h/sqrt(2m x KE).

What is the unit of de Broglie wavelength?

It is a length, so the SI unit is the metre (m). For electrons and atoms the values are tiny, around 10^-10 m (angstrom scale), which is why matter waves are only noticeable for very small particles.

Who gave the de Broglie hypothesis and when?

Louis de Broglie proposed it in 1924. He suggested that all moving matter has an associated wave of wavelength lambda = h/p. It was later confirmed by the Davisson-Germer experiment showing electron diffraction.

Why do large objects not show wave behaviour?

Because lambda = h/p and h is extremely small. A cricket ball has a large momentum p, making lambda around 10^-34 m, far too small to ever observe. Wave nature is only significant for tiny masses like electrons.

Is the de Broglie relation the same for a photon?

Yes, lambda = h/p holds for a photon too. For a photon momentum p = E/c, so its de Broglie wavelength equals its ordinary electromagnetic wavelength.