What Is a p-n Junction? Formation and Meaning

Physics · Semiconductor Electronics : Materials, Devices And Simple Circuits · NEET

A p-n junction is the single piece of semiconductor where a p-type region (extra holes) meets an n-type region (extra electrons). It is not two slabs glued together, it is one crystal doped differently on each side. Where they meet, electrons and holes cross over (diffusion), leave behind fixed charged ions, and set up a built-in barrier potential that stops the flow. Memory hook: "p meets n in one crystal, they swap carriers, and a wall (barrier) is born."
p-type (holes +)n-type (electrons -)depletion region+ + ++ +- - -- -- --+ ++Fixed ions build barrier potential V0 (Ge ~0.3 V, Si ~0.7 V)Diffusion current = Drift current at equilibrium (net current = 0)
One crystal doped p on the left and n on the right. Near the junction carriers cross over, leaving fixed positive ions on the n-side and negative ions on the p-side. This charge-free depletion region sets up the barrier potential V0, and at equilibrium diffusion and drift currents cancel.

Your doubts, answered

Is a p-n junction just a p-slab and an n-slab pressed together?

No. NCERT is clear on this. If you press two flat slabs together, the surface roughness is far larger than the atomic spacing (about 2 to 3 angstrom), so there is no continuous contact at the atomic level. Charge carriers cannot flow smoothly across such a gap. A real p-n junction is made from ONE crystal: you start with a p-type wafer and add a pentavalent impurity to part of it, turning that part into n-type. The boundary inside this single crystal is the metallurgical junction.

What actually happens right where p meets n?

Two processes happen together. Diffusion: the n-side is crowded with electrons and the p-side is crowded with holes, so holes move p to n and electrons move n to p because of the concentration difference. This gives a diffusion current. Drift: as electrons leave the n-side they leave behind fixed positive donor ions, and as holes leave the p-side they leave behind fixed negative acceptor ions. These fixed ions set up an electric field that pushes carriers back. That field-driven motion is the drift current.

Why does a barrier potential build up on its own?

When an electron leaves the n-side it exposes a fixed positive ion; when a hole leaves the p-side it exposes a fixed negative ion. So the n-side near the junction becomes positive and the p-side near the junction becomes negative. This charge separation creates a potential difference across the junction, called the barrier potential (built-in potential V0). Its polarity opposes further crossing of carriers. Typical value is about 0.3 V for germanium and about 0.7 V for silicon.

Does current keep flowing across the junction forever?

No. At the start, diffusion current is large and drift current is small. As more carriers cross, the fixed-ion (space-charge) regions grow, the electric field gets stronger, so drift current rises. This continues until diffusion current exactly equals drift current. At that point the net current is zero and the junction is in equilibrium. So an isolated p-n junction carries NO net current on its own.

What is the difference between diffusion current and drift current here?

Diffusion current is due to majority carriers moving because of a concentration difference (holes p to n, electrons n to p). Drift current is due to the built-in electric field sweeping minority carriers the other way (n to p direction of field). At equilibrium these two are equal and opposite, so they cancel. Under bias (applied voltage) one dominates, which is how a diode conducts or blocks.

⚠️ The NEET trap
You can make a p-n junction by physically joining a p-type slab to an n-type slab, and current keeps flowing across a junction at equilibrium.
A p-n junction is one crystal doped on both sides (joined slabs never touch at atomic level per NCERT Example 14.3), and at equilibrium diffusion current equals drift current so NET current is zero.
🧠 One crystal, not two slabs. Equilibrium means zero NET current, not zero motion.

Real NEET questions

2021

Consider Statements A and B: A. A zener diode is connected in reverse bias when used as a voltage regulator. B. The potential barrier of a p-n junction lies between 0.1 V to 0.3 V. Identify the correct answer.

A · A is correct, B is incorrect
B · A is incorrect but B is correct
C · A and B both are correct
D · A and B both are incorrect
Solution: Statement A: a zener diode does operate in reverse bias as a voltage regulator, so A is correct. Statement B: the barrier potential of a p-n junction is small (for germanium about 0.3 V), which lies within the 0.1 V to 0.3 V band, so per the official key B is taken as correct. Hence both statements are correct. Answer C.
2020

The increase in the width of the depletion region in a p-n junction diode is due to:

A · Both forward bias and reverse bias
B · Increase in forward current
C · Forward bias only
D · Reverse bias only
Solution: The depletion region is the layer of fixed ions around the junction. Under reverse bias the applied field points the same way as the built-in field, so it sweeps more carriers away from the junction and exposes more fixed ions. This widens the depletion region. Forward bias does the opposite and narrows it. So the width increases only under reverse bias. Answer D.

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Frequently asked

What is a p-n junction in simple words?

It is one semiconductor crystal that is p-type on one side and n-type on the other, with a boundary in between. At that boundary carriers cross over and a built-in barrier forms.

How is a p-n junction formed?

Start with a p-type silicon wafer and add a small amount of pentavalent impurity to part of it, converting that part to n-type. Diffusion and drift then create the junction and its barrier potential.

What is the barrier potential of a p-n junction?

About 0.3 V for germanium and about 0.7 V for silicon. It is the built-in voltage V0 that opposes further diffusion of carriers across the junction.

Does a p-n junction conduct current on its own?

No. At equilibrium the diffusion current and drift current are equal and opposite, so the net current is zero until an external voltage (bias) is applied.

Why can't we just glue a p-slab and an n-slab together?

Surface roughness is much larger than atomic spacing, so there is no atomic-level contact. The gap behaves as a discontinuity and carriers cannot flow across it properly.