Atomic Number and Mass Number: Definition, Formula and Difference

Chemistry · Structure Of Atom · NEET

Atomic number (Z) is the number of protons in an atom's nucleus. Mass number (A) is the total number of protons and neutrons together. So the number of neutrons = A minus Z. Memory hook: "Z counts protons, A counts the heavy stuff (protons + neutrons)." In a neutral atom, electrons also equal Z.
Element Symbol: what the numbers meanXAZA = Mass number= protons + neutronsZ = Atomic number= number of protonsKey formulasProtons = ZElectrons = Z(neutral atom only)Neutrons = A - Z
In an element symbol, the top-left number is the mass number A (protons + neutrons) and the bottom-left number is the atomic number Z (protons). Neutrons are found by A minus Z.

Your doubts, answered

Is the atomic number the number of protons or the number of electrons?

Atomic number (Z) is defined as the number of protons in the nucleus. In a NEUTRAL atom, the number of electrons happens to equal the number of protons, so electrons = Z too. But the identity of the element is fixed only by protons. If the atom becomes an ion, its electrons change but the atomic number stays the same. So the safe rule: Z = protons always, Z = electrons only when the atom is neutral.

What is the difference between atomic number and mass number?

Atomic number (Z) counts only protons. Mass number (A) counts protons AND neutrons together. Z tells you WHICH element it is (it never changes for a given element). A tells you how heavy that particular atom is, and it can differ for atoms of the same element (these are isotopes). Quick check: A is always bigger than or equal to Z, because A includes Z plus the neutrons.

How do I find the number of neutrons?

Use the formula: neutrons = mass number minus atomic number, or n = A minus Z. Example: for an atom with A = 23 and Z = 11 (sodium), neutrons = 23 minus 11 = 12. Never subtract electrons here. Neutrons only depend on A and Z, so ions do not change the neutron count.

What do the top and bottom numbers on an element symbol mean?

An element is written as (A on top-left, Z on bottom-left) X. The TOP number is the mass number A (protons + neutrons). The BOTTOM number is the atomic number Z (protons). Example: for lutetium written as Lu with 175 on top and 71 on the bottom, A = 175 and Z = 71. Many students swap them, so remember: bottom is the smaller number (protons), top is the bigger number (total nucleons).

Does the atomic number change when an atom becomes an ion?

No. When an atom gains or loses electrons to form an ion, only the electron count changes. The number of protons stays the same, so the atomic number Z does NOT change, and the mass number A does not change either. Example: Na (11 protons, 11 electrons) becomes Na+ (11 protons, 10 electrons). Z is still 11 for both.

Why is mass number always a whole number but atomic mass is not?

Mass number A is just a COUNT of protons plus neutrons, so it must be a whole number (you cannot have half a neutron). Atomic mass (the value on the periodic table, like 35.5 for chlorine) is a weighted AVERAGE of all the isotopes' masses, so it comes out as a decimal. Do not confuse mass number (a count) with atomic mass (an average). NEET uses mass number for proton-neutron problems.

⚠️ The NEET trap
For the atom written as Lu with 175 on top and 71 on the bottom, the neutrons = 175 (mass number is the number of neutrons).
Neutrons = A minus Z = 175 minus 71 = 104. Protons = Z = 71, and electrons (neutral atom) = 71 as well. So protons : neutrons : electrons = 71 : 104 : 71.
🧠 Mass number is NOT the neutron count. Always subtract: neutrons = A minus Z. This exact trap appeared in NEET 2020.

Real NEET questions

NEET 2020

The number of protons, neutrons and electrons in the atom lutetium (written as Lu with mass number 175 on top and atomic number 71 on the bottom), respectively, are:

A · 71, 71 and 104
B · 175, 104 and 71
C · 71, 104 and 71
D · 104, 71 and 71
Solution: Here mass number A = 175 and atomic number Z = 71. Protons = Z = 71. Electrons (neutral atom) = Z = 71. Neutrons = A minus Z = 175 minus 71 = 104. So the order protons, neutrons, electrons = 71, 104, 71, which is option C. The trap is picking B, which wrongly reads 175 as the proton count.
NEET 2021

Magnesium reacts with an element X to form an ionic compound. If the ground-state electronic configuration of X is 1s2 2s2 2p3, the simplest formula for this compound is:

A · Mg2X
B · MgX2
C · Mg2X3
D · Mg3X2
Solution: The configuration 1s2 2s2 2p3 has 7 electrons, so the neutral atom X has atomic number Z = 7 (that is nitrogen, with 5 valence electrons). X gains 3 electrons to form X 3-, and Mg forms Mg 2+. Cross-combining the charges (2 and 3) gives the formula Mg3X2, option D. This shows how atomic number fixes the element's identity and valency.

Solved Structure Of Atom NEET PYQs

Try the real previous-year questions from this chapter — each with the answer and a full solution.

See all 30 Structure Of Atom NEET PYQs ›
Next concept: Difference Between Isotopes, Isobars and Isotones (NEET)Keep learning — 2 minFeeling ready? Solve the Structure Of Atom NEET PYQs ›Or practice on your phone — get the free MedicNEET app ›

Frequently asked

What is the atomic number and mass number in simple words?

Atomic number (Z) is the number of protons in the nucleus, and it decides which element the atom is. Mass number (A) is the total number of protons plus neutrons, and it tells you how heavy the atom is.

What is the formula linking atomic number, mass number and neutrons?

Mass number = protons + neutrons, so A = Z + n. Rearranged, neutrons = mass number minus atomic number, n = A minus Z.

Can two atoms have the same atomic number but different mass numbers?

Yes. Atoms of the same element have the same Z but can have different numbers of neutrons, so they have different mass numbers A. These are called isotopes (for example carbon-12 and carbon-14).

Is mass number the same as atomic mass?

No. Mass number is a whole-number count of protons plus neutrons for one atom. Atomic mass is the weighted average mass of all natural isotopes, so it is usually a decimal like 35.5 for chlorine.

Why does the atomic number never change for an element?

Because Z equals the number of protons, and the number of protons is what defines the element. Changing the protons would change the element itself. Gaining or losing electrons (making an ion) or neutrons (making an isotope) does not change Z.