Emissivity, Absorptivity and Kirchhoff's Law

Physics · Thermal Properties Of Matter · NEET

Kirchhoff's law says a good absorber of radiation is also a good emitter. In symbols, at a given temperature a body's emissivity equals its absorptivity (e = a). Emissivity e (0 to 1) tells what fraction of black-body radiation a surface emits, so its power is E = e sigma A T^4. Memory hook: "Whatever a surface drinks in, it must give back out."
Kirchhoff's Law: Good Absorber = Good EmitterBlacke = a ~ 1Shinye = a ~ 0absorbs inemits outlittle inlittle outE = e sigma A T^4
A black surface absorbs and emits strongly (e = a near 1); a shiny surface does both weakly (e = a near 0). Emissivity e scales the black-body power to give E = e sigma A T^4.

Your doubts, answered

What exactly is emissivity and what values can it take?

Emissivity (e) is a pure number from 0 to 1. It compares how much a real surface radiates to how much a perfect black body radiates at the same temperature. A perfect black body has e = 1 (best emitter). A perfect reflector has e = 0. Human skin has e about 0.97, so it emits almost like a black body. Power radiated becomes E = e sigma A T^4, where sigma = 5.67 x 10^-8 W m^-2 K^-4.

What is absorptivity and how is it different from emissivity?

Absorptivity (a) is the fraction of radiation falling on a surface that the surface absorbs (rest is reflected or transmitted). It is also a number from 0 to 1. Emissivity is about giving OUT radiation; absorptivity is about taking IN radiation. Kirchhoff's law links them: at the same temperature and wavelength, e = a. So they are two views of the same property of the surface.

What does Kirchhoff's law of radiation state?

Kirchhoff's law says: at a given temperature, the ratio of emissive power to absorptive power is the same for all bodies and equals the emissive power of a perfect black body. A short way to say it: a good absorber is a good emitter (e = a). This is why the inside of a hollow cavity behaves like a black body, and why dark surfaces both heat up fast in sunlight and cool fast at night.

Why is a good absorber also a good emitter?

Think of a body in a closed box at fixed temperature (thermal equilibrium). To stay at the same temperature it must emit exactly as much energy as it absorbs. A surface that absorbs a lot must therefore also emit a lot, otherwise it would keep heating up or cooling down. That balance forces emissivity to equal absorptivity. So black (high absorber) = high emitter; shiny silver (low absorber) = low emitter.

How do I calculate power radiated when emissivity is given?

Use E = e sigma A T^4 for total power emitted, where T is the absolute (Kelvin) temperature. If you want NET rate of heat exchange with surroundings at temperature T0, use P_net = e sigma A (T^4 - T0^4). Always convert Celsius to Kelvin first by adding 273. Example: for skin at 307 K, area 1.5 m^2, e = 0.97, surroundings 293 K, plug in T = 307 and T0 = 293 in P_net = e sigma A (T^4 - T0^4).

⚠️ The NEET trap
A good absorber of heat is a good reflector, so a black surface emits poorly.
A good absorber is a good EMITTER (e = a). A black surface absorbs well AND emits well; a shiny surface both reflects and emits poorly.
🧠 NTA loves swapping 'emitter' with 'reflector'. Remember: absorb well = emit well, never reflect well.

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Frequently asked

What is the unit of emissivity?

Emissivity has no unit. It is a pure ratio between 0 and 1, comparing a real surface to a perfect black body at the same temperature.

What is the emissivity of a perfect black body?

A perfect black body has emissivity e = 1. It absorbs all radiation falling on it and emits the maximum possible radiation at its temperature.

Are emissivity and absorptivity always equal?

By Kirchhoff's law they are equal at the same temperature and same wavelength when the body is in thermal equilibrium. This equality e = a is the core result used in NEET problems.

Why does a black car get hotter in the sun than a white car?

Black paint has high absorptivity, so it absorbs more sunlight and heats up more. By Kirchhoff's law it also emits more, but during the day absorption dominates, so the black car gets hotter.

How does emissivity change the Stefan-Boltzmann formula?

For a black body power is sigma A T^4. For a real body multiply by emissivity: E = e sigma A T^4. Since e is less than 1, a real body radiates less than a black body at the same temperature.