Comparing Isothermal, Adiabatic, Isobaric and Isochoric on a P-V Graph

Physics · Thermodynamics · NEET

On a P-V graph from the same start point: isochoric is a vertical line (constant V), isobaric is a horizontal line (constant P), isothermal is a falling curve (PV = constant), and adiabatic is a steeper falling curve (PV^gamma = constant). Memory hook: "Vertical Volume, Horizontal Pressure, Adiabatic Always steeper." The adiabatic is steeper than the isothermal because gamma is greater than 1.
VPA (start)Isochoric (V fixed)Isobaric (P fixed)Isothermal PV=constAdiabatic PV^g=const (steeper)
Four processes from one common start point A: isochoric (vertical), isobaric (horizontal), isothermal (gentle falling curve) and adiabatic (steeper falling curve, diving below the isotherm).

Your doubts, answered

How do I quickly spot each of the four processes on one P-V graph?

Look at the shape of the line starting from the common point. A vertical straight line means volume is not changing, so it is isochoric. A horizontal straight line means pressure is not changing, so it is isobaric. A falling curve means both P and V change; of the two falling curves the less steep one is isothermal and the steeper one is adiabatic. So: vertical = isochoric, horizontal = isobaric, gentle curve = isothermal, steep curve = adiabatic.

Why is the adiabatic curve steeper than the isothermal curve?

The slope of a curve on a P-V graph tells how fast pressure falls as volume grows. Isothermal follows PV = constant, so its slope is proportional to minus P over V. Adiabatic follows PV^gamma = constant, so its slope is proportional to minus gamma times P over V. Since gamma (Cp/Cv) is always greater than 1, the adiabatic slope is gamma times larger in size. At the same point the adiabatic line drops faster, so it is steeper. The ratio of slopes is exactly gamma.

In an adiabatic expansion, does the gas get hotter or colder?

It gets colder. In an adiabatic process no heat enters or leaves (Q = 0). When the gas expands it does work on the surroundings, and that work energy can only come from the internal energy of the gas. Losing internal energy means the temperature falls. This is why in the NEET 2023 PYQ the statement T_C > T_A after adiabatic expansion is wrong; the correct result is T_C < T_A.

Which process does the maximum work when a gas expands from the same start?

Work done by the gas equals the area under the P-V curve between the two volumes. Because the isobaric line stays high (constant pressure), then the isothermal falls a bit, and the adiabatic falls fastest, the areas rank as: isobaric > isothermal > adiabatic > isochoric (isochoric does zero work because volume does not change). So for equal expansion, isobaric gives the most work and isochoric gives none.

Do the curves cross each other, and what does the crossing point mean?

All four processes here start from one common point, so they all meet there. The isothermal and adiabatic both leave that point going down-right, but the adiabatic dives below the isothermal because it is steeper. After the start point they separate and do not meet again in normal expansion. The common start point is just the shared initial state (same P, V, T) before the gas is taken along four different paths.

⚠️ The NEET trap
Thinking the isothermal curve is steeper than the adiabatic, or mixing up which straight line (vertical vs horizontal) is isochoric.
Adiabatic is always steeper (slope ratio = gamma > 1). Vertical line = isochoric (constant V); horizontal line = isobaric (constant P).
🧠 Adiabatic Always dives; Vertical = Volume fixed.

Real NEET questions

NEET 2022

An ideal gas undergoes four different processes from the same initial state. The processes are adiabatic, isothermal, isobaric and isochoric. The curve which represents the adiabatic process among curves 1, 2, 3, 4 is (curve 1 is vertical, curve 4 is horizontal, curves 2 and 3 are falling curves with 2 steeper than 3):

A · 1
B · 2
C · 3
D · 4
Solution: Step 1: Identify the straight lines. Curve 1 is vertical, so volume is constant, meaning it is isochoric. Curve 4 is horizontal, so pressure is constant, meaning it is isobaric. Step 2: The two falling curves (2 and 3) must be isothermal and adiabatic. Step 3: Isothermal follows PV = constant with slope proportional to minus P over V. Adiabatic follows PV^gamma = constant with slope proportional to minus gamma times P over V. Since gamma > 1, the adiabatic is steeper. Step 4: Curve 2 is the steeper falling curve, so curve 2 is adiabatic. Answer: option B (2).
NEET 2023

Reversible expansion of an ideal gas is shown, where AB is isothermal expansion and AC is adiabatic expansion, both starting from common state A. Which option is NOT correct?

A · S_isothermal > S_adiabatic
B · T_A = T_B
C · W_isothermal > W_adiabatic
D · T_C > T_A
Solution: Step 1: Check each statement. In reversible isothermal expansion the gas absorbs heat, so entropy rises (dS > 0). In reversible adiabatic expansion Q = 0, so dS = 0. Hence S_isothermal > S_adiabatic is correct. Step 2: AB is isothermal, so temperature is constant, giving T_A = T_B correct. Step 3: On the P-V graph the adiabat AC is steeper and lies below the isotherm AB, so area under AB > area under AC, meaning W_isothermal > W_adiabatic is correct. Step 4: In adiabatic expansion the gas does work using its own internal energy, so temperature falls: T_C < T_A. Therefore T_C > T_A is wrong. Answer: option D.
NEET 2017

A P-V diagram shows three isotherms at 700 K, 500 K and 300 K. Four processes I, II, III, IV start from a common state (I is a vertical line, II is a steep falling curve crossing to a lower-temperature isotherm, III runs along an isotherm, IV is a horizontal line). Match each process with its type: (a) Adiabatic, (b) Isobaric, (c) Isochoric, (d) Isothermal.

A · I to a, II to c, III to d, IV to b
B · I to c, II to a, III to d, IV to b
C · I to d, II to a, III to c, IV to b
D · I to b, II to c, III to a, IV to d
Solution: Step 1: Process I is a vertical line, so volume is constant: isochoric (c). Step 2: Process IV is a horizontal line, so pressure is constant: isobaric (b). Step 3: Process III runs along a single isotherm (same temperature curve): isothermal (d). Step 4: Process II is a steep falling curve that crosses from a higher to a lower temperature isotherm; an adiabat is steeper than an isotherm and cools on expansion, so it is adiabatic (a). Matching: I to c, II to a, III to d, IV to b. Answer: option B.

Solved Thermodynamics NEET PYQs

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Frequently asked

What is the order of steepness of the four processes on a P-V graph?

From least steep to most steep for the changing-volume processes: isobaric (horizontal, slope zero), then isothermal (gentle falling curve), then adiabatic (steeper falling curve), then isochoric (vertical, slope infinite). So isochoric is the steepest possible line and isobaric is the flattest.

Why does the isochoric process do no work?

Work done by a gas equals pressure times change in volume, and it is the area under the P-V line. In an isochoric process volume does not change, so there is no area under a vertical line. Therefore work done is zero and all the heat goes into changing internal energy (Q = dU).

Is the adiabatic slope exactly gamma times the isothermal slope?

Yes. At the same point on the graph, the adiabatic slope equals gamma multiplied by the isothermal slope in magnitude. For a monatomic gas gamma is about 1.67 and for a diatomic gas about 1.40, so the adiabatic is roughly 1.4 to 1.7 times steeper at that point.

On the same P-V graph, which expansion cools the gas most?

The adiabatic expansion. Isothermal keeps temperature constant, isobaric expansion actually raises temperature (V rises at constant P so T rises), and adiabatic expansion lowers temperature because the gas spends internal energy doing work with no heat coming in.

How is this different from work-done formulas for each process?

This page is about reading and comparing the shapes on the graph. The next concept, work done in different processes, gives the exact formulas: W = P.dV for isobaric, W = nRT ln(V2/V1) for isothermal, W = (P1V1 - P2V2)/(gamma - 1) for adiabatic, and W = 0 for isochoric.