ReNEET 2026 · Chemistry · Q67The d- and f-Block ElementsIn our bank: Strong match · 88%

The lanthanide ion having four unpaired electrons is: (Atomic numbers: Ce =58, Nd =60, Tb =65, Ho =67)

  1. A.Nd³⁺
  2. B.Ce³⁺
  3. C.Tb³⁺
  4. D.Ho³⁺

Correct Answer

(D) Ho³⁺

Solution & Explanation

For a lanthanide ion Ln³⁺ the electronic configuration is [Xe]4f^n; find n, then count unpaired electrons in the 7 f-orbitals by Hund's rule (fill singly first up to 7, then pair). Ce³⁺ (Z=58): 4f¹ ⇒ 1 unpaired. Nd³⁺ (Z=60): 4f³ ⇒ 3 unpaired. Tb³⁺ (Z=65): 4f⁸ ⇒ 7 singly-filled then 1 paired ⇒ 6 unpaired. Ho³⁺ (Z=67): 4f¹⁰ ⇒ 7 orbitals each get one electron, then 3 pair up, leaving 7 − 3 = 4 unpaired. The ion with exactly four unpaired electrons is Ho³⁺. Answer: option D.

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