NEET 2016 Phase 2 · ChemistryCarbonyl reductionPrevious Year Question
The correct structure of the product formed in the following reaction is:
Answer: (B) (B). \textbf{Answer:} (B) cyclohexanone \textbf{Solution:} In cyclohex-2-en-1-one, catalytic hydrogenation with /Pd-C at low pressure (1 atm) selectively reduces the less hindered, more reactive double bond while leaving the carbonyl group intact.

- A.(A)
- B.(B)✓
- C.(C)
- D.(D)
Correct Answer
(B) (B)
Solution & Explanation
\textbf{Answer:} (B) cyclohexanone \textbf{Solution:} In cyclohex-2-en-1-one, catalytic hydrogenation with /Pd-C at low pressure (1 atm) selectively reduces the less hindered, more reactive double bond while leaving the carbonyl group intact. The conjugated alkene of the enone is hydrogenated, so the product is cyclohexanone. The carbonyl is not reduced under these mild conditions.
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