NEET 2023 Phase 2 · ChemistryVBT and MOPrevious Year Question

Which one of the following statements is incorrect related to Molecular Orbital Theory?

Answer: (A) Molecular orbitals obtained from and orbitals are symmetrical around the bond axis.. \textbf{Answer:} (A) Molecular orbitals obtained from and orbitals are symmetrical around the bond axis.

  1. A.Molecular orbitals obtained from and orbitals are symmetrical around the bond axis.
  2. B.A -bonding molecular orbital has larger electron density above and below the internuclear axis.
  3. C.The antibonding molecular orbital has a node between the nuclei.
  4. D.In the formation of a bonding molecular orbital, the two electron waves of the bonding atoms reinforce each other.

Correct Answer

(A) Molecular orbitals obtained from and orbitals are symmetrical around the bond axis.

Solution & Explanation

\textbf{Answer:} (A) Molecular orbitals obtained from and orbitals are symmetrical around the bond axis. \textbf{Solution:} Lateral (sidewise) overlap of (or ) orbitals gives molecular orbitals, which are NOT symmetrical about the bond axis; only the axial overlap gives a MO symmetrical around the bond axis. Hence statement (A) is incorrect.

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