Einstein's Photoelectric Equation

Physics · Dual Nature Of Radiation And Matter · NEET

Einstein's photoelectric equation is Kmax = h*v - phi_0, which means the maximum kinetic energy of an ejected electron equals the photon energy (h*v) minus the work function (phi_0). One photon gives all its energy to one electron: part is spent escaping the metal, the rest becomes kinetic energy. Memory hook: "Photon pays the exit fee (phi_0), the change is Kmax."
Einstein's Photoelectric Equation: energy balancephotonenergy = h vMetal surfaceexit fee = phi_0(work function)e-Kmax = h v - phi_0leftover energy = speedeV: E = 1240 / lambda(nm)
One photon (energy h*v) hits the metal; the electron pays the exit fee phi_0 (work function) and keeps the leftover as maximum kinetic energy Kmax = h*v - phi_0.

Your doubts, answered

What does each term in Kmax = hv - phi_0 mean?

h*v is the energy carried by ONE photon (h = Planck's constant 6.63e-34 J.s, v = frequency). phi_0 is the work function, the minimum energy an electron needs to escape the metal surface. Kmax is the maximum kinetic energy of the fastest ejected electron. In simple words: photon energy in, exit fee (phi_0) paid, leftover energy becomes motion. If h*v is less than phi_0, no electron comes out.

Why does Kmax NOT depend on intensity of light?

In Einstein's photon picture, one electron absorbs exactly one photon. The photon's energy depends only on its frequency (h*v), not on how many photons there are. Intensity means more photons per second, so more electrons are ejected (higher current), but each electron still gets the energy of a single photon. So intensity raises the NUMBER of electrons, not their maximum energy. This is why Kmax depends on frequency and work function only.

How do I use the equation quickly in eV?

Use the shortcut E = 1240 / lambda, where E is in eV and lambda (wavelength) is in nanometres. So photon energy in eV = 1240/lambda(nm). Then Kmax(eV) = 1240/lambda - phi_0(eV). Example: light of 400 nm on a metal with phi_0 = 2.0 eV gives E = 1240/400 = 3.1 eV, so Kmax = 3.1 - 2.0 = 1.1 eV. This saves you from converting joules every time.

What is the difference between h*v, phi_0 and Kmax?

h*v is the TOTAL energy delivered by the photon. phi_0 is the FIXED energy cost to leave the metal (a property of the metal only). Kmax is what is LEFT OVER for the electron's speed. Think of a toll road: h*v is the money you carry, phi_0 is the toll, Kmax is the money left after paying. If your money (h*v) is below the toll (phi_0), you cannot even enter, so no emission.

Why is the Kmax versus frequency graph a straight line?

Rewrite the equation as Kmax = h*v - phi_0, which is in the form y = m*x + c with x = frequency, slope m = h (Planck's constant, same for all metals) and intercept c = -phi_0. So plotting Kmax against frequency gives a straight line: its slope gives h, and where it cuts the frequency axis (Kmax = 0) gives the threshold frequency v_0 = phi_0/h.

⚠️ The NEET trap
Doubling the intensity of light doubles the maximum kinetic energy of the photoelectrons.
Doubling intensity doubles the photoelectric current (number of electrons) but Kmax stays exactly the same, because Kmax = h*v - phi_0 depends only on frequency and work function.
🧠 Intensity changes HOW MANY electrons come out, frequency changes HOW FAST they come out.

Real NEET questions

2016

Photons with energy 5 eV are incident on a cathode C in a photoelectric cell. The maximum energy of emitted photoelectrons is 2 eV. When photons of energy 6 eV are incident on C, no photoelectrons will reach the anode A if the stopping potential of A relative to C is:

A · +3 V
B · +4 V
C · -1 V
D · -3 V
Solution: Step 1: Find the work function from the first case. Kmax = E - phi_0, so 2 = 5 - phi_0, giving phi_0 = 3 eV. Step 2: Apply Einstein's equation for 6 eV photons. Kmax = 6 - 3 = 3 eV. Step 3: To stop these electrons, the stopping potential must satisfy e*V0 = Kmax = 3 eV, so |V0| = 3 V. Since anode A must be negative relative to C to repel the electrons, the stopping potential is -3 V. Answer: -3 V.
2018

When light of frequency 2v_0 (v_0 is the threshold frequency) is incident on a metal plate, the maximum velocity of electrons is v1. When the frequency is increased to 5v_0, the maximum velocity is v2. The ratio v1 : v2 is:

A · 4 : 1
B · 1 : 4
C · 1 : 2
D · 2 : 1
Solution: Step 1: Use Kmax = h*v - h*v_0 (since phi_0 = h*v_0). Step 2: For the first case, (1/2)m*v1^2 = h(2v_0) - h*v_0 = h*v_0. Step 3: For the second case, (1/2)m*v2^2 = h(5v_0) - h*v_0 = 4h*v_0. Step 4: Divide: v1^2 / v2^2 = (h*v_0)/(4h*v_0) = 1/4. Take square root: v1 : v2 = 1 : 2. Answer: 1 : 2.
2023

The maximum kinetic energy of the emitted photoelectrons in the photoelectric effect is independent of:

A · Frequency of incident radiation
B · Wavelength of incident radiation
C · Work function of material
D · Intensity of incident radiation
Solution: Einstein's equation Kmax = h*v - phi_0 shows Kmax depends on frequency v (and therefore on wavelength, since v = c/lambda) and on the work function phi_0. It does NOT contain intensity. Intensity only sets how many photons arrive per second, which changes the number of ejected electrons (the current), not their maximum energy. Answer: Intensity of incident radiation.

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Frequently asked

What is Einstein's photoelectric equation?

It is Kmax = h*v - phi_0. The maximum kinetic energy of a photoelectron equals the photon energy h*v minus the work function phi_0 of the metal. It expresses energy conservation for one photon absorbed by one electron.

What is the eV shortcut for photon energy?

Photon energy in eV = 1240 / lambda, where lambda is the wavelength in nanometres. So Kmax(eV) = 1240/lambda(nm) - phi_0(eV). This lets you solve NEET numericals fast without converting to joules.

What is the threshold frequency in this equation?

When Kmax = 0, the photon energy just equals the work function: h*v_0 = phi_0, so v_0 = phi_0/h. Below this threshold frequency v_0, no electrons are emitted no matter how intense or how long the light shines.

Why did Einstein win the Nobel Prize for this?

He explained three facts that the wave theory could not: Kmax depends on frequency (not intensity), there is a threshold frequency, and emission is instantaneous. His photon idea (light as energy packets h*v) was confirmed by Millikan's experiments, which also gave an accurate value of Planck's constant.

What is the relation between Kmax and stopping potential?

The stopping potential V0 is the voltage that just stops the fastest electron, so e*V0 = Kmax. Therefore Einstein's equation can be written as e*V0 = h*v - phi_0. Measuring V0 for different frequencies lets you find h from the graph slope.