Maximum Kinetic Energy of Photoelectrons

Physics · Dual Nature Of Radiation And Matter · NEET

The maximum kinetic energy of photoelectrons is the highest energy an ejected electron can have. It is Kmax = hv - phi0, which also equals eV0 (charge times stopping potential). So Kmax depends only on the frequency of light and the metal's work function. Memory hook: "More frequency, more Kmax; more brightness, only more electrons."
Frequency v (of incident light)Kmaxv0 (threshold)Kmax = hv - phi0slope = hNo emission(hv below phi0)Higher v gives higher Kmax; intensity does NOT shift this line
Kmax rises as a straight line with frequency, Kmax = hv - phi0. The line starts at the threshold frequency v0 (where Kmax = 0) and its slope is Planck's constant h. Changing intensity does not move this line; only frequency and work function do.

Your doubts, answered

Does intensity affect the maximum kinetic energy of photoelectrons?

No. Kmax = hv - phi0 has no intensity term in it. If you make the light brighter (more intense) but keep the same colour (same frequency), each photon still carries the same energy hv, so each electron still gets the same maximum push. Brighter light only sends MORE photons per second, so MORE electrons come out (higher current). It does not make any single electron faster. This is one of the most tested NEET facts.

What is the formula for maximum kinetic energy of a photoelectron?

Kmax = hv - phi0, where h is Planck's constant, v is the frequency of the incident light, and phi0 is the work function of the metal. It can also be written using wavelength as Kmax = hc/lambda - phi0. Because the stopping potential V0 just stops the fastest electron, Kmax = eV0 as well. All three forms describe the same quantity.

Why does Kmax equal eV0 (electron charge times stopping potential)?

The stopping potential V0 is the reverse voltage that is just strong enough to turn back even the fastest photoelectron. To stop that electron, the electric field must do work equal to its kinetic energy. Work done on charge e across potential V0 is eV0. Setting this equal to the fastest electron's energy gives eV0 = Kmax. So measuring V0 in an experiment directly gives you Kmax.

Does Kmax depend on wavelength or frequency?

Both, because they are linked by c = v times lambda. Kmax rises linearly with frequency v (Kmax = hv - phi0). In terms of wavelength, Kmax = hc/lambda - phi0, so shorter wavelength (which means higher frequency) gives larger Kmax. NEET may phrase it either way, so be ready to convert using v = c/lambda.

What happens to Kmax if the frequency is doubled?

Kmax does NOT simply double. Kmax = hv - phi0 is a straight line, not a proportional relation. If Kmax = hv - phi0 at frequency v, then at frequency 2v it becomes 2hv - phi0, which is more than double the old Kmax but less than 2 times (Kmax + hv). Only the hv part doubles; the work function phi0 stays fixed. Always plug into the equation, do not just scale.

Can Kmax be negative?

No. If the photon energy hv is less than the work function phi0, then no electron is emitted at all, so Kmax has no meaning (it is not a negative number, it is simply zero emission). Photoemission only starts when hv is at least phi0, that is when frequency reaches the threshold frequency v0. At exactly v0, Kmax = 0.

⚠️ The NEET trap
Increasing the intensity (brightness) of the light increases the maximum kinetic energy of the photoelectrons.
Increasing intensity only increases the number of photoelectrons (the current). Kmax depends only on frequency and work function: Kmax = hv - phi0.
🧠 Intensity controls HOW MANY electrons, frequency controls HOW FAST. NEET 2023 asked exactly this: Kmax is independent of intensity.

Real NEET questions

NEET 2023 (Phase 2)

The maximum kinetic energy of the emitted photoelectrons in the photoelectric effect is independent of:

A · Frequency of incident radiation
B · Wavelength of incident radiation
C · Work function of material
D · Intensity of incident radiation
Solution: Einstein's equation: Kmax = hv - phi0. Kmax depends on frequency v (and hence wavelength) and on the work function phi0. It does NOT contain intensity. Intensity only changes the number of photoelectrons (the current), not their maximum energy. So Kmax is independent of intensity. Answer: (D).
NEET 2016 (Phase 2)

Photons with energy 5 eV are incident on a cathode C in a photoelectric cell. The maximum energy of emitted photoelectrons is 2 eV. When photons of energy 6 eV are incident on C, no photoelectrons will reach the anode A if the stopping potential of A relative to C is:

A · +3 V
B · +4 V
C · -1 V
D · -3 V
Solution: Step 1: Find the work function. Kmax = E - phi0, so 2 = 5 - phi0, giving phi0 = 3 eV. Step 2: New photon energy is 6 eV, so new Kmax = 6 - 3 = 3 eV. Step 3: To stop the fastest electron, eV0 = Kmax = 3 eV, so V0 = 3 V. Since the anode A must be negative relative to C to repel the electrons, the stopping potential is -3 V. Answer: (D).
NEET 2016 (Phase 1)

When a metallic surface is illuminated with radiation of wavelength lambda, the stopping potential is V. If the same surface is illuminated with radiation of wavelength 2 lambda, the stopping potential is V/4. The threshold wavelength for the metallic surface is:

A · 4 lambda
B · 5 lambda
C · (5/2) lambda
D · 3 lambda
Solution: Use eV0 = hc/lambda - phi0. Case 1: eV = hc/lambda - phi0. Case 2: e(V/4) = hc/(2 lambda) - phi0. Multiply case 2 by 4: eV = 2hc/lambda - 4 phi0. Set equal to case 1: hc/lambda - phi0 = 2hc/lambda - 4 phi0, so 3 phi0 = hc/lambda, giving phi0 = hc/(3 lambda). Threshold: hc/lambda0 = phi0 = hc/(3 lambda), so lambda0 = 3 lambda. Answer: (D).

Solved Dual Nature Of Radiation And Matter NEET PYQs

Try the real previous-year questions from this chapter — each with the answer and a full solution.

See all 28 Dual Nature Of Radiation And Matter NEET PYQs ›
Next concept: Stopping Potential vs Frequency GraphKeep learning — 2 minFeeling ready? Solve the Dual Nature Of Radiation And Matter NEET PYQs ›Or practice on your phone — get the free MedicNEET app ›

Frequently asked

What is the maximum kinetic energy of a photoelectron in simple words?

It is the largest amount of movement energy that an electron kicked out by light can have. Electrons deep inside the metal lose some energy escaping, so they come out slower; the ones right at the surface lose the least and come out fastest. That fastest electron's energy is Kmax = hv - phi0.

How do I calculate Kmax quickly in eV?

Use the shortcut: photon energy in eV = 1240 / (wavelength in nm). Then Kmax = (1240/lambda_nm) - phi0(eV). For example, light of 300 nm on a metal of work function 2 eV gives photon energy 1240/300 = 4.13 eV, so Kmax = 4.13 - 2 = 2.13 eV.

What is the difference between Kmax and stopping potential?

Kmax is an energy (measured in joules or eV). Stopping potential V0 is a voltage (in volts) that just stops the fastest electron. They are linked by Kmax = eV0. If you know V0 in volts, Kmax in eV is numerically the same number, because e times V0 gives energy eV0.

Why do only the fastest electrons matter for Kmax?

Emitted electrons have a range of energies, from nearly zero up to a maximum. The word 'maximum' refers to the surface electrons that escape most easily. In experiments, the stopping potential is set to turn back even these fastest ones, so it measures Kmax, the top of the range.

Is Kmax the same for all metals under the same light?

No. Under the same frequency of light, a metal with a smaller work function phi0 gives a larger Kmax, because Kmax = hv - phi0. For example caesium (low phi0) gives faster electrons than sodium (higher phi0) for the same incident light.