Volume Expansion and Coefficient of Cubical Expansion

Physics · Thermal Properties Of Matter · NEET

When you heat a solid or liquid, its volume grows. The coefficient of cubical (volume) expansion, written gamma (gamma), tells you the fraction of volume gained per 1 degree Celsius rise. The rule is delta V = gamma V delta T, where V is the starting volume and delta T is the temperature rise. Memory hook: gamma is the "3D brother" of linear alpha, and for a solid gamma = 3 alpha.
Volume Expansion of a Cube on HeatingVCool (T)V + delta VHot (T + delta T)heatdelta V =gamma V delta Tgamma = 3 alpha(solids)
On heating from T to T + delta T, a body of volume V gains delta V = gamma V delta T. The dashed outline shows the original size; gamma is the fractional volume gain per degree, equal to 3 alpha for an isotropic solid.

Your doubts, answered

What exactly is the coefficient of cubical (volume) expansion gamma?

It is the fractional change in volume per unit rise in temperature. In symbols, gamma = (delta V / V) / delta T, so delta V = gamma V delta T. Example: if gamma = 5 x 10^-5 per degree C and you heat 1 litre of oil by 20 degrees C, the extra volume is delta V = (5 x 10^-5)(1000 cm^3)(20) = 1 cm^3.

What is the SI unit of gamma?

Per kelvin (K^-1), which is the same size of unit as per degree Celsius (per degree C), because a change of 1 K equals a change of 1 degree C. Gamma is a small number for solids and liquids, so it is written with powers of ten, like 2 x 10^-5 K^-1.

Is gamma always equal to 3 alpha?

For an isotropic solid (same expansion in every direction) yes, gamma = 3 alpha, and also beta = 2 alpha. But liquids and gases have no alpha, so gamma is measured directly for them. For anisotropic crystals the three directions differ, and gamma equals the sum of the three separate linear coefficients.

Does the volume increase depend on the shape of the object?

No. delta V = gamma V delta T uses only the volume V, not the shape. A cube, sphere, or irregular blob of the same material and same starting volume all gain the same delta V for the same delta T. Only V, gamma, and delta T matter.

Why is gamma of liquids much larger than gamma of solids?

In a liquid the particles are loosely bound and free to move, so heating pushes them apart more easily than in a tightly bonded solid. That is why gamma for liquids is typically 10 times or more larger than gamma for solids, which is why a liquid overflows a container that was heated together with it.

⚠️ The NEET trap
Using gamma = 3 alpha for a liquid or a gas.
gamma = 3 alpha only for an isotropic solid. Liquids and gases have no linear coefficient alpha; their gamma is measured on its own (and for an ideal gas at constant pressure gamma = 1/T).
🧠 3 alpha is a solid-only shortcut. If the question says liquid or gas, do not split gamma into alpha.

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Frequently asked

What is the formula for volume expansion?

delta V = gamma V delta T, where delta V is the increase in volume, gamma is the coefficient of cubical expansion, V is the original volume, and delta T is the rise in temperature. The final volume is V' = V (1 + gamma delta T).

What is the value of gamma for common substances?

For most solids gamma is around 1 x 10^-5 to 7 x 10^-5 K^-1. For liquids it is larger, for example mercury is about 18 x 10^-5 K^-1 and water is about 21 x 10^-5 K^-1 near room temperature. Gases have a much larger gamma, about 3.7 x 10^-3 K^-1.

How is gamma related to the change in density?

Since mass stays the same but volume grows, density falls on heating. Approximately, new density = old density / (1 + gamma delta T), which for small delta T is about old density x (1 - gamma delta T). This is why hot fluids are lighter and rise.

Is gamma a constant for a material?

For solids and most liquids gamma is nearly constant over an ordinary temperature range, so we treat it as fixed for NEET numericals. It can vary at very high temperatures and near phase changes, and water is a special case (anomalous expansion below 4 degrees C).