Carnot Engine Efficiency: eta = 1 - T2/T1 Derivation

Physics · Thermodynamics · NEET

A Carnot engine takes heat Q1 from a hot source at temperature T1 and rejects heat Q2 to a cold sink at temperature T2. Its efficiency is eta = 1 - Q2/Q1, and because the cycle is reversible, Q2/Q1 = T2/T1, giving the famous result eta = 1 - T2/T1 (with T in kelvin). Memory hook: "Sink over Source, subtract from one" - efficiency is 1 minus (sink temperature / source temperature).
Hot sourceT1 (high)Cold sinkT2 (low)CarnotengineQ1 inQ2 outW = Q1 - Q2eta = W / Q1= (Q1 - Q2) / Q1= 1 - Q2/Q1= 1 - T2/T1(T in kelvin, reversible)
A Carnot engine absorbs heat Q1 from a hot source at T1, does work W, and rejects Q2 to a cold sink at T2. Since the cycle is reversible, Q2/Q1 = T2/T1, so eta = 1 - Q2/Q1 = 1 - T2/T1.

Your doubts, answered

Why does Q2/Q1 turn into T2/T1 for a Carnot engine?

In the Carnot cycle the heat is exchanged only during the two isothermal steps. Using the isothermal work formula, heat taken from the source is Q1 = nR T1 ln(V2/V1) and heat given to the sink is Q2 = nR T2 ln(V3/V4). For the two adiabatic steps, the relation T V^(gamma-1) = constant makes the volume ratios equal, so V2/V1 = V3/V4. The logarithm terms cancel, leaving Q2/Q1 = T2/T1. That is the key step that replaces heats with temperatures.

Why must T1 and T2 be in kelvin, not celsius?

The formula eta = 1 - T2/T1 comes from an ideal gas relation where temperature is absolute (measured from 0 K). If you put celsius values, the ratio T2/T1 is wrong. Always convert first: T(K) = T(deg C) + 273. For example 100 deg C becomes 373 K, not 100.

What is the difference between eta = 1 - Q2/Q1 and eta = 1 - T2/T1?

eta = 1 - Q2/Q1 is the general definition for ANY heat engine (efficiency = work done / heat taken = (Q1 - Q2)/Q1). eta = 1 - T2/T1 is a SPECIAL result that is true only for a reversible Carnot engine, because only then Q2/Q1 equals T2/T1. For a real engine Q2/Q1 is larger than T2/T1, so its efficiency is lower.

Does the efficiency depend on which gas is used or how much gas there is?

No. The number of moles n and the gas constant R cancel out when we take the ratio Q2/Q1. Carnot's theorem states the efficiency of a Carnot engine is independent of the working substance. It depends only on the two temperatures T1 and T2.

Why is it sink over source (T2/T1) and not source over sink?

Because efficiency is fraction of heat converted to work: eta = W/Q1 = (Q1 - Q2)/Q1 = 1 - Q2/Q1. The rejected (wasted) heat Q2 sits on top, so the smaller temperature T2 goes on top. A smaller T2/T1 ratio means less heat wasted and higher efficiency.

⚠️ The NEET trap
Plugging source and sink temperatures in degrees Celsius straight into eta = 1 - T2/T1.
Convert both to kelvin first (add 273), then take the ratio. Example: source 327 deg C = 600 K, sink 27 deg C = 300 K, so eta = 1 - 300/600 = 0.5 = 50%.
🧠 Celsius in the ratio is the number one Carnot mistake. Kelvin first, always.

Real NEET questions

NEET 2018

The efficiency of an ideal heat engine working between the freezing point and boiling point of water is:

A · 6.25%
B · 20%
C · 26.8%
D · 12.5%
Solution: Freezing point T2 = 0 + 273 = 273 K, boiling point T1 = 100 + 273 = 373 K. For an ideal (Carnot) engine eta = 1 - T2/T1 = 1 - 273/373 = 100/373 = 0.268 = 26.8%. So the answer is (C).
NEET 2023

A Carnot engine has an efficiency of 50% when its source is at 327 deg C. The temperature of the sink is:

A · 27 deg C
B · 15 deg C
C · 100 deg C
D · 200 deg C
Solution: Source T1 = 327 + 273 = 600 K. Using eta = 1 - T2/T1 with eta = 0.50: 0.50 = 1 - T2/600, so T2/600 = 0.50, giving T2 = 300 K. Convert back: T2 = 300 - 273 = 27 deg C. Answer (A).
NEET 2017

A Carnot engine having an efficiency of 1/10 as a heat engine is used as a refrigerator. If the work done on the system is 10 J, the amount of energy absorbed from the reservoir at lower temperature is:

A · 1 J
B · 90 J
C · 99 J
D · 100 J
Solution: As a heat engine eta = W/Q1 = 1/10, so Q1 = 10W. Run in reverse as a refrigerator with work input W = 10 J: heat rejected to hot reservoir Q1 = 10 x 10 = 100 J. By the first law for the cycle Q2 = Q1 - W = 100 - 10 = 90 J. This is the heat absorbed from the cold reservoir. Answer (B).

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Frequently asked

What is the formula for Carnot engine efficiency?

eta = 1 - T2/T1, where T1 is the source (hot) temperature and T2 is the sink (cold) temperature, both in kelvin. Equivalently eta = 1 - Q2/Q1 in terms of heat.

Can Carnot efficiency ever be 100%?

No. eta = 1 - T2/T1 equals 1 (100%) only if T2 = 0 K (absolute zero) or T1 is infinite. Both are impossible, so real efficiency is always below 100%. This links to the second law of thermodynamics.

Is efficiency higher when the temperature difference is larger?

Yes. A bigger gap between T1 and T2 (a hotter source or a colder sink) makes the ratio T2/T1 smaller, so eta = 1 - T2/T1 is larger.

Does the Carnot efficiency depend on the working gas?

No. By Carnot's theorem the efficiency depends only on T1 and T2, not on the type or amount of gas. The moles n and constant R cancel in the derivation.

Why is the Carnot engine the most efficient engine?

Because it is reversible. No engine working between the same two temperatures can beat a Carnot engine. Any real (irreversible) engine wastes more heat and has lower efficiency.