Why Can Carnot Engine Efficiency Never Be 100%?

Physics · Thermodynamics · NEET

Carnot efficiency is eta = 1 - T2/T1. To get 100% (eta = 1) you would need the sink temperature T2 to be 0 kelvin (absolute zero), or the source T1 to be infinite. Both are impossible, so some heat is always rejected to the sink and efficiency stays below 1. Memory hook: "No zero sink, no full work" - as long as T2 is above 0 K, T2/T1 is a real positive number, so 1 minus it is always less than 1.
Heat Engine: some heat is always rejectedHot source T1gives heat Q1EngineW = Q1 - Q2Cold sink T2takes heat Q2 (never 0)Work Weta = W/Q1 = 1 - T2/T1 < 1 because T2 > 0 K
Because the sink temperature T2 is always above absolute zero, the engine must reject heat Q2, so work W is less than Q1 and efficiency eta = 1 - T2/T1 stays below 100%.

Your doubts, answered

Why does eta = 1 - T2/T1 never give 1?

For eta to equal 1, the fraction T2/T1 must be 0. A fraction is zero only when its top (T2) is zero. So the sink would need T2 = 0 K, which is absolute zero. Absolute zero cannot be reached, so T2 is always a positive kelvin value. That makes T2/T1 a small positive number, and 1 minus a positive number is always less than 1. Efficiency stays below 100%.

Why can't we just make the source T1 infinite instead?

If T1 goes to infinity, T2/T1 goes to 0 and eta goes to 1 in theory. But no real reservoir can have infinite temperature. Real sources like steam or furnace gases have finite T1 (a few hundred to a thousand kelvin). With finite T1 and finite T2, the ratio T2/T1 is always a real positive number, so eta is always below 1.

Why must a heat engine always reject heat to the cold sink?

By the Kelvin-Planck statement of the second law (NCERT): no process can take heat from one reservoir and turn all of it into work with no other change. So the engine must dump some heat Q2 to the sink. Work done W = Q1 - Q2. Since Q2 is never zero, W is always less than Q1, so efficiency eta = W/Q1 is always less than 1.

Does the first law allow 100% efficiency? Then why is it banned?

The first law (energy conservation) alone would allow 100% efficiency - it only says energy is conserved, not the direction of flow. NCERT notes many processes obey the first law yet never happen. The second law is the extra rule that forbids full conversion of heat into work. So 100% efficiency does not break energy conservation; it breaks the second law.

Is efficiency in the formula a fraction or a percentage?

The formula eta = 1 - T2/T1 gives a fraction (a number between 0 and 1). To write it as a percentage, multiply by 100. For example, if T2/T1 = 0.732, then eta = 0.268 = 26.8%. Always put T1 and T2 in kelvin before dividing, never in Celsius.

⚠️ The NEET trap
Students put source and sink temperatures in Celsius, so an engine between 100 C and 0 C looks like eta = 1 - 0/100 = 100%.
Convert to kelvin first: T1 = 373 K, T2 = 273 K, so eta = 1 - 273/373 = 0.268 = 26.8%, not 100%.
🧠 T2/T1 is only zero if T2 = 0 K. In Celsius, 0 C is 273 K, not zero - so efficiency is never 100% for real temperatures.

Real NEET questions

NEET 2018

The efficiency of an ideal heat engine working between the freezing point and boiling point of water is

A · 6.25%
B · 20%
C · 26.8%
D · 12.5%
Solution: Step 1: Convert both temperatures to kelvin. Freezing point (sink) T2 = 0 + 273 = 273 K. Boiling point (source) T1 = 100 + 273 = 373 K. Step 2: Apply Carnot (ideal) efficiency: eta = 1 - T2/T1 = 1 - 273/373. Step 3: 273/373 = 0.732, so eta = 1 - 0.732 = 0.268 = 26.8%. Note it is far below 100% because the sink T2 = 273 K is not zero. Answer: C.
NEET 2023

A Carnot engine has an efficiency of 50% when its source is at 327 C. The temperature of the sink is

A · 27 C
B · 15 C
C · 100 C
D · 200 C
Solution: Step 1: Source in kelvin T1 = 327 + 273 = 600 K. Step 2: eta = 1 - T2/T1, with eta = 0.50, so 0.50 = 1 - T2/600. Step 3: T2/600 = 0.50, giving T2 = 300 K. Step 4: Convert back: T2 = 300 - 273 = 27 C. Even at 50% here, reaching 100% would need T2 = 0 K, which is impossible. Answer: A.

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Frequently asked

What is the exact reason Carnot efficiency is never 100%?

Because eta = 1 - T2/T1 equals 1 only if T2 = 0 K (absolute zero) or T1 = infinity. Neither is physically possible, so T2/T1 is always a positive number and efficiency stays below 1.

Which law forbids 100% efficiency?

The second law of thermodynamics, in the Kelvin-Planck form: no process can convert all the heat absorbed from a reservoir into work with no other change. The first law (energy conservation) does not forbid it.

Can any real engine beat the Carnot engine?

No. Carnot's theorem (NCERT) states no engine working between the same two temperatures can have efficiency greater than the Carnot engine. Real engines are less efficient due to friction and irreversibility.

What would efficiency be if the sink were at absolute zero?

If T2 = 0 K, then eta = 1 - 0/T1 = 1 = 100%. But absolute zero cannot be reached, so this is only a theoretical limit, never achieved.

Does higher source temperature or lower sink temperature help more?

Both increase efficiency because they lower the ratio T2/T1. Raising T1 or lowering T2 pushes eta closer to 1, but it can never reach 1 for finite T1 and T2 above 0 K.