First Law of Thermodynamics: Statement, Formula and Meaning

Physics · Thermodynamics · NEET

The First Law of Thermodynamics says heat given to a system is used to change its internal energy and to do work. In formula form: Q = dU + W, where Q is heat added, dU is change in internal energy, and W is work done by the system. Memory hook: "Heat In = Energy stored + Work done out." It is just the law of conservation of energy for heat.
First Law: Q = dU + W (Energy Conservation)SYSTEMdU = Q - WQ (heat in)positiveW (work out)gas expandsHeat In = Energy Stored (dU) + Work Done Out (W)
Heat added (Q) to a system either raises its internal energy (dU) or is used to do work (W) as the gas expands. Q = dU + W.

Your doubts, answered

Is the formula Q = dU + W or Q = dU - W? I keep mixing them up.

Both are correct, but they use different sign meanings for W. The NCERT/NEET standard form is Q = dU + W, where W is work done BY the gas (on the surroundings). Rearranged, dU = Q - W. Some books write Q = dU - W when W means work done ON the gas. Stick to the NEET convention: Q = heat added to system, W = work done by system, so Q = dU + W. Memorize the words, not just letters: heat in equals energy stored plus work done out.

What is the real difference between Q, W and dU?

Q (heat) and W (work) are energy in transit (path functions) - they only exist during a process and depend on the path taken. dU (change in internal energy) is a state function - it depends only on the starting and ending temperature, not the path. So two different paths between the same two states can have different Q and different W, but always the same dU.

Does the First Law tell us which direction a process will go?

No. The First Law only says energy is conserved. It does not forbid heat flowing from cold to hot, or a gas cooling itself to do work. It is silent about direction and feasibility. That job belongs to the Second Law of Thermodynamics. The First Law is a bookkeeping rule: energy in must equal energy out plus energy stored.

Why is dU zero in a cyclic process even though Q and W are not zero?

Internal energy U is a state function. In a cyclic process the gas returns to its exact starting state (same P, V, T), so its internal energy is unchanged: dU = 0. Then the First Law gives Q = W. All the net heat absorbed comes out as net work. This is the working idea behind heat engines.

For an ideal gas, what does the change in internal energy dU actually depend on?

For an ideal gas, internal energy depends ONLY on temperature. So dU = n Cv dT for ANY process (not just constant volume). If temperature does not change (isothermal process), dU = 0 for an ideal gas, no matter how the volume or pressure changes. This is why in an isothermal process Q = W.

⚠️ The NEET trap
Writing Q = dU + W but plugging in work done ON the gas as positive W during expansion.
In Q = dU + W, W is work done BY the gas. When the gas expands, W is positive; when it is compressed, W is negative. If the problem gives 'work done on the gas', flip the sign before using it.
🧠 Gas pushes out = positive W. Gas gets squeezed = negative W.

Real NEET questions

2026

At a certain temperature, during a process, 500 J is absorbed by the system and 200 J of work is done by the system. The change in internal energy of the system is:

A · 400 J
B · 300 J
C · 700 J
D · 500 J
Solution: By the First Law of Thermodynamics, dU = Q - W. Here Q = +500 J (heat absorbed by the system) and W = +200 J (work done by the system). So dU = 500 - 200 = 300 J. Both signs are positive because heat goes into the system and the system does work outward.
2026

An electric heater supplies heat to a system at a rate of 100 W. If the system performs work at a rate of 75 J/s, the rate at which internal energy increases is:

A · 75 W
B · 100 W
C · 125 W
D · 25 W
Solution: Use the First Law in rate form: dQ/dt = dU/dt + dW/dt. Here dQ/dt = 100 W (heat supplied per second) and dW/dt = 75 J/s (work done per second). So dU/dt = dQ/dt - dW/dt = 100 - 75 = 25 W. The internal energy grows at 25 watts.

Solved Thermodynamics NEET PYQs

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Frequently asked

What is the First Law of Thermodynamics in one line?

Heat supplied to a system equals the increase in its internal energy plus the work done by the system: Q = dU + W. It is the law of conservation of energy applied to heat.

What is the formula of the First Law and what does each term mean?

Q = dU + W. Q is heat added to the system (joules), dU is the change in internal energy, and W is the work done by the system. Rearranged: dU = Q - W.

What is the sign convention used in Q = dU + W?

Q is positive when heat is added to the system, negative when heat leaves. W is positive when the gas expands (does work on surroundings), negative when it is compressed. dU is positive when temperature (internal energy) rises.

Is the First Law valid for all processes?

Yes. Q = dU + W holds for every thermodynamic process - isothermal, adiabatic, isobaric, isochoric and cyclic - and for any substance, because it is just energy conservation.

What is the First Law for an isochoric (constant volume) process?

At constant volume no work is done (W = 0), so Q = dU. All the heat added goes into raising internal energy and temperature.

What is the limitation of the First Law?

It tells us energy is conserved but not the direction a process takes or whether it is feasible. It does not explain why heat flows from hot to cold. The Second Law fills this gap.